Abstract
The interaction of gas phase endohedral fullerene Ho(3)N@C(80) with intense (0.1-5 × 10(14) W/cm(2)), short (30 fs), 800 nm laser pulses was investigated. The power law dependence of Ho(3)N@C(80)(q+), q = 1-2, was found to be different from that of C(60). Time-dependent density functional theory computations revealed different light-induced ionization mechanisms. Unlike in C(60,) in doped fullerenes, the breaking of the cage spherical symmetry makes super atomic molecular orbital (SAMO) states optically active. Theoretical calculations suggest that the fast ionization of the SAMO states in Ho(3)N@C(80) is responsible for the n = 3 power law for singly charged parent molecules at intensities lower than 1.2 × 10(14) W/cm(2).