Synthesis, crystal structure and Hirshfeld surface analysis of 3-ethyl-2-(methyl-sulfan-yl)-5,5-diphenyl-3H-imidazol-4(5H)-one (Thio-phenytoin analogue)

3-乙基-2-(甲硫基)-5,5-二苯基-3H-咪唑-4(5H)-酮(硫代苯妥英类似物)的合成、晶体结构和Hirshfeld表面分析

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Abstract

In the title mol-ecule, 3-ethyl-2-(methyl-sulfan-yl)-5,5-diphenyl-3H-imidazol-4(5H)-one, C(18)H(18)N(2)OS, the two substituent phenyl rings are inclined of 59.50 (7) and 83.53 (8)° with respect to the plane of the five-membered ring. The S-methyl group lies in this plane while the ethyl group is nearly perpendicular to it. In the crystal, weak C-H⋯O hydrogen bonds form inversion dimers, which pack via conventional van der Waals contacts. A Hirshfeld surface analysis was performed, showing the predominance of H⋯H and C⋯H/H⋯C contacts.

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