Green-Emitting Lead-Free Cs(4)SnBr(6) Zero-Dimensional Perovskite Nanocrystals with Improved Air Stability

具有改进空气稳定性的绿色发光无铅Cs(4)SnBr(6)零维钙钛矿纳米晶体

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Abstract

We report the synthesis and characterization of nanocrystals of a novel fully inorganic lead-free zero-dimensional perovskite, Cs(4)SnBr(6). Samples are made of crystals with an average size of ∼20 nm with green emission centered around 530 nm. Interestingly, both colloidal suspensions and thin films show an enhanced air stability with respect to that of any other previous tin-based nanocrystalline system, with emission persisting for tens of hours under laboratory air.

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