Ti Reactive Sintering of Electrically Conductive Al(2)O(3)–TiN Composite: Influence of Ti Particle Size and Morphology on Electrical and Mechanical Properties

钛反应烧结制备导电Al₂O₃-TiN复合材料:钛颗粒尺寸和形貌对电学和力学性能的影响

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Abstract

In the current study, Al(2)O(3)–TiN composites were successfully fabricated with various particle sizes (10, 20, 30, and 50 μm) and concentrations (5, 10, 15, and 20 vol %) via a novel ball milling + Ti reactive sintering process. By applying the reactive sintering, Ti powders will transform into TiN particles, which act as mechanical reinforcements and electrical conductors in the Al(2)O(3) matrix. The ball milling process alters the Ti powder morphology from a low-aspect-ratio sphere into a high-aspect-ratio disc, which reduces the electrical percolation threshold value from 29% to 15% in the current setup. However, such a threshold value is insensitive to the particle size. Meanwhile, the Ti particle size has a significant influence on the material’s mechanical properties. A small particle size results in less porosity and hence higher flexural strength of the composite.

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