Revealing the global emission gaps for fully fluorinated greenhouse gases

揭示全球完全氟化温室气体的排放缺口

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Abstract

In response to the global trend of climate change, it is important to accurately quantify emissions of fully fluorinated greenhouse gases (FFGHGs, referring to SF(6)/NF(3)/CF(4)/C(2)F(6)/C(3)F(8)/c-C(4)F(8) here). Atmospheric observation-based top-down methods and activity-based bottom-up methods are usually used together to estimate FFGHG emissions at the global and regional levels. In this work, emission gaps at global and regional levels are discussed among top-down studies, between the top-down and bottom-up FFGHG emissions, and among bottom-up emissions. Generally, trends and magnitudes of individual FFGHG emissions among top-down estimates are close to each other within the uncertainties. However, global bottom-up inventories show discrepancies in FFGHG emissions among each other in trends and magnitudes. The differences in emission magnitudes are up to 93%, 90%, 88%, 83%, 87%, and 85% for SF(6), NF(3), CF(4), C(2)F(6), C(3)F(8), and c-C(4)F(8), respectively. Besides, we reveal the insufficient regional TD studies and the lack of atmospheric observation data/stations especially in areas with potential FFGHG emissions. We make recommendations regarding the best practices for improving our understanding of these emissions, including both top-down and bottom-up methods.

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