Large interlayer spacing Nb(4)C(3)T (x) (MXene) promotes the ultrasensitive electrochemical detection of Pb(2+) on glassy carbon electrodes

较大的层间距Nb₄C₃Tₓ(MXene)促进了玻碳电极上Pb²⁺的超灵敏电化学检测。

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Abstract

A Nb(4)C(3)T (x) (MXene)-modified glassy carbon electrode was used for the electrochemical detection of Pb(2+) ions in aqueous media. The sensing platform was evaluated by anodic stripping analysis after optimizing the influencing factors such as pH, deposition potential, and time. The large interlayer spacing, high c lattice parameter and higher conductivity of Nb(4)C(3)T (x) compared to other MXenes enhance the electrochemical detection of Pb(2+). The developed sensor can reach a detection limit of 12 nM at a potential ∼-0.6 V. Additionally, the developed sensor showed promising selectivity in the presence of Cu(2+) and Cd(2+), and stability for at least 5 cycles of continuous measurements with good repeatability. This work demonstrates the potential applications of Nb(4)C(3)T (x) towards the development of effective electrochemical sensors.

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