The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study

Nd₂O₃掺杂CuO纳米粒子的光催化性能及其对亚甲基蓝降解的增强作用:合成、表征和对比研究

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Abstract

The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd(2)O(3) doped CuO) nanoparticles by combustion method for effective degradation of dye, methylene blue (MB). X-ray diffraction (XRD), Field emission Scanning electron microscopy (FESEM), Zeta potential have been applied for characterization. Photocatalyst validity has been evaluated for methylene blue degradation (MB). Test conditions such as time of contact, H(2)O(2), pH, and photo-Fenton have been modified to identify optimal degradation conditions. Noticeably, 7.5% Nd(2)O(3) doped CuO nanoparticle demonstrated the highest photocatalytic efficiency, up to 90.8% in 80 min, with a 0.0227 min(-1) degradation rate. However, the photocatalytic efficiency at pH 10 becomes 99% with a rate constant of 0.082 min(-1). Cyclic experiments showed the Nd(2)O(3) doped CuO nanoparticle's stability over repeated use. Scavenge hydroxyl radical species responsible for degradation using 7.5% Nd(2)O(3) doped CuO nanoparticles have been investigated under visible irradiation.

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