Surpassing Shockley-Queisser Efficiency Limit in Photovoltaic Cells

超越光伏电池的肖克利-奎伊瑟效率极限

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Abstract

The Shockley-Queisser (S-Q) model sets a theoretical limit on the power conversion efficiency (PCE) of single-junction solar cells at around 33%. Recently, a PCE of 50%-60% was achieved for the first time in n-type single-junction Si solar cells by inhibiting light conversion to heat at low temperatures. Understanding these new observations opens tremendous opportunities for designing solar cells with even higher PCE to provide efficient and powerful energy sources for cryogenic devices and outer and deep space explorations.

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