Cu-catalyzed cross-dehydrogenative coupling: a versatile strategy for C-C bond formations via the oxidative activation of sp(3) C-H bonds

铜催化交叉脱氢偶联：一种通过sp(3) CH键氧化活化形成C-C键的通用策略

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作者：Li,Zhiping,Bohle,D Scott,Li,Chao-Jun
期刊：Proceedings of the National Academy of Sciences of the United States of America影响因子：9.100
时间：2006起止号：2006 Jun 13;103(24):8928-33
doi：10.1073/pnas.0601687103

Abstract

Cu-catalyzed cross-dehydrogenative coupling (CDC) methodologies were developed based on the oxidative activation of sp(3) C-H bonds adjacent to a nitrogen atom. Various sp, sp(2), and sp(3) C-H bonds of pronucleophiles were used in the Cu-catalyzed CDC reactions. Based on these results, the mechanisms of the CDC reactions also are discussed.

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