Engineering Characteristics of Cement Composites Containing a Chitosan-Based Polymer and Steel Slag Aggregates

壳聚糖基聚合物与钢渣骨料水泥基复合材料的工程特性

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作者:Se-Jin Choi, Sung-Ho Bae, Hoe Young Choi, Haye Min Ko

Abstract

Recently, sustainable development has attracted significant global attention. Toward this, several studies have been performed on the development of alternative aggregates for mortar or concrete to prevent environmental damage and rapid depletion of natural aggregates. In this study, we investigated the applicability of a chitosan-based polymer (CBP), a biomimetic polymer, to cement mortar using steel slag as a fine aggregate. The CBP was synthesized via an amide coupling reaction among chitosan, 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride, and 3-(3,4-dihydroxyphenyl)propionic acid. Upon addition to cement mortar using natural sand or a blast furnace slag aggregate, the CBP contributed toward increasing the compressive strength and tensile strength. However, in mortar mixes using a ferronickel slag aggregate, the tensile strength decreased by ~5.7-25.4% upon CBP addition. Moreover, the CBP reduced the total charge passed through the mixes. In particular, in the mortar mix using the steel slag aggregate, the CBP showed improved chloride-ion penetration resistance. The results showed that the as-prepared CBP was a suitable improving agent and exhibited promising compatibility with cement composites containing steel slag aggregates.

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