trans-Di-chlorido-bis-(dimethyl sulfoxide-κO)bis-(4-fluoro-benzyl-κC(1))tin(IV): crystal structure and Hirshfeld surface analysis

反式-二氯双-(二甲基亚砜-κO)双-(4-氟苄基-κC(1))锡(IV):晶体结构和Hirshfeld表面分析

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Abstract

The Sn(IV) atom in the title diorganotin compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(2)H(6)OS)(2)], is located on a centre of inversion, resulting in the C(2)Cl(2)O(2) donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H⋯F, C-H⋯Cl and C-H⋯π inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl⋯H/H⋯Cl and F⋯H/H⋯F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.

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