Abstract
The title compound, [Cd(2)(C(8)H(8)NS(2))(4)], is a centrosymmetric dimer with both chelating and μ(2)-tridentate di-thio-carbamate ligands. The resulting S(5) donor set defines a Cd(II) coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.