Technological research of process for producing titanium rich slag and complex titanium-containing ferroalloy

富钛渣和复杂含钛铁合金生产工艺的技术研究

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Abstract

This paper demonstrates the results on the experimental smelting of the titanium rich slag and complex titanium-containing ferroalloy under the large-scale laboratory conditions that simulate industrial one. The technological researches of the process were performed on an ore-thermal furnace with 200 kVA transformer power. The titanium rich slag was produced from the low-grade ilmenite concentrate, i.e. the low TiO(2) content and the high content of impurities. During the production of the high-grade titanium slag (TiO(2) content: 75-80%), the impurity elements are transferred into the associated alloyed metal (cast iron). Thus, it can be used to smelt the steel. As a result, samples of titanium slag have been produced with the content of the main components, %: TiO(2) - 80.2; Al(2)O(3) - 4.5; SiO(2) - 1.97; Cr(2)O(3) - 1.3 and Fe(2)O(3) - 9.87. Then, in metallurgical practice a complex titanium-containing ferroalloy was first smelted from the previously produced titanium rich slag using a carbothermic approach. The high-ash coal was applied as a carbon-bearing reducing agent. The ash was more 45%. As a result of tests, a pilot batch of the alloy was produced with the following chemical composition, %: Ti - 20-25; Si - 35-45; Al - 10-15; C - 0.2-0.5; P - no more than 0.08; and ferrum. The main component content in the produced alloy suggests that it can serve as an alternative to a mechanical mixture (FeSi45, aluminum shavings, low-percentage ferrotitanium) for steel alloying and deoxidation purposes.

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