Synergistic catalytic mechanism of red mud in the co-gasification of spirit-based distillers' grains and sewage sludge

赤泥在酒精基酒糟与污水污泥共气化中的协同催化机制

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Abstract

Experiments of co-gasification of spirit-based distillers' grains (SDG) and sewage sludge (SS) were carried out with red mud (RM) by using a self-designed fixed-bed gasifier. The effects of RM addition, gasification reaction temperature, SS and SDG blending ratio and other factors on the gasification reaction characteristics and synergism were investigated. The results are as follow: RM had catalytic effect on SS and SDG co-gasification, which can enhance the gasification reaction and H(2) yield; increasing the temperature can enhance the gasification reaction and reduce the syngas H(2)/CO; with the increase of SDG, the H(2) yield gradually grew; with the rise of SS, the gasification reaction gradually augmented. The catalytic mechanism was mainly due to the redox cycle of Fe(2)O(3) in RM, which can promote the water transfer reaction. At the same time, the eutectic mixture of K, Na, Ca, Fe and other metal elements at high temperatures was the main reason for the synergistic effect.

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