Selective Hydrothermal Leaching of Aluminum from Al(3)YRh (x) (x = 0, 0.2, 0.5, 1.0) Intermetallic Compounds: The Effect of Rh Variants in Comparing the Catalytic CO Oxidation and CO-PROX Reactions

从 Al(3)YRh (x) (x = 0, 0.2, 0.5, 1.0) 金属间化合物中选择性水热浸出铝:Rh 变体对催化 CO 氧化和 CO-PROX 反应的影响比较

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Abstract

Wealth from modern civilization and globalization accelerates natural resource extraction and damages the Earth's environment. Elevated mute assassin "carbon monoxide (CO)" levels impede aerobic life. We need to develop limiting technologies to overcome these constraints. Stern environmental agreements to reduce CO levels are significant. In this work, a hydrothermal leaching (HyTL) of Al(3)Y-Rh (x) (x = 0, 0.2, 0.5, 1.0) intermetallic compounds yields Y(OH)(3) products with well-distributed rhodium (Rh). The HyTL method and active Rh element improved HyTL Al(3)Y-Rh(0.5) catalytic CO oxidation and the preferential oxidation of the CO (CO-PROX) performance. Metal-support interactions and HyTL Al(3)Y-Rh(0.5) catalyst synergy produce oxygen vacancies, govern CO oxidation, and standardize oxygen mobility. This is essential to the synthesized catalyst's improved catalytic performance. All low-temperature instances of Rh have strong catalytic activity. This study advances CO catalytic oxidation and CO-PROX over the HyTL Al(3)Y-Rh(0.5) catalyst, ensuring the aggregation-activation process. The findings support an understanding of low-temperature catalytic systems.

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