The non-centrosymmetric polymorph of (quinolin-8-ol-κ(2) N,O)(quinolin-8-olato-κ(2) N,O)silver(I)

(喹啉-8-醇-κ(2) N,O)(喹啉-8-醇-κ(2) N,O)银(I)的非中心对称多晶型

阅读:2

Abstract

The title compound, [Ag(C9H6NO)(C9H7NO)], crystallizes as a non-centrosymmetric polymorph. The structure was previously reported by Wu et al. [(2006). Acta Cryst. E62, m281-m282] in the centrosymmetric space group Pbcn. The Ag(I) ion displays a distorted tetra-hedral coordination geometry defined by two N and two O atoms from a neutral quinolin-8-ol ligand (HQ) and a deprotonated quinolin-8-olate anion (Q(-)). The dihedral angle between the two ligands is 47.0 (1)°. Strong O-H⋯O hydrogen bonds link the mol-ecules into a supra-molecular chain along the a-axis direction.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。