Low-cost CoFe(2)O(4)/biomass carbon hybrid from metal-enriched sulfate reducing bacteria as an electrocatalyst for water oxidation

低成本CoFe(2)O(4)/生物质碳复合材料(源自富金属硫酸盐还原菌)作为水氧化电催化剂

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Abstract

The development of electrocatalysts for the Oxygen Evolution Reaction (OER) requires extensive and challenging research for the water splitting and fuel cell applications. Herein, we report a low-cost CoFe(2)O(4)/biomass carbon (CFO@BC/Zn) hybrid from Co-enriched Sulfate Reducing Bacteria (Co-SRB) as an electrocatalyst for OER. The electrocatalyst exhibits a low potential of 1.53 V at a current density 10 mA cm(-2) and Tafel slope of 86 mV dec(-1). This method does not require high-cost or long periods of preparation. The density-functional theory (DFT) calculations show a small barrier for oxygen conversion on Fe(3+) of CFO (100) surface. The synthesis of CFO@BC/Zn may be a new approach for obtaining low-priced electrocatalysts for OER.

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