Abstract
We report two BNB-type frustrated Lewis pairs which feature an acceptor-donor-acceptor functionalized cavity, and which differ in the nature of the B-bound fluoroaryl group (C(6) F(5) vs. C(6) H(3) (CF(3) )(2) -3,5, Ar(f) ). These receptor systems are capable of capturing gaseous CO, and in the case of the -BAr(f) (2) system this can be shown to occur in reversible fashion at/above room temperature. For both systems, the binding event is accompanied by migration of one of the aryl substituents to the electrophilic carbon of the CO guest. Experiments utilizing an additional equivalent of P(t) Bu(3) allow the initially formed (non-migrated) CO adduct to be identified and trapped (via demethylation), while also establishing the reversibility of the B-to-C migration process. When partnered with the slightly less Lewis acidic -BAr(f) (2) substituent, this reversibility allows for release of the captured carbon monoxide in the temperature range 40-70 °C, and the possibility for CO sensing, making use of the associated colourless to orange/red colour change.