Beyond Reppe: building substituted arenes by [2+2+2] cycloadditions of alkynes

超越雷佩:通过炔烃的[2+2+2]环加成反应构建取代芳烃

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Abstract

Synthetic sequel: The transition-metal-catalyzed [2+2+2] cycloaddition is an established method for the construction of carbocyclic frameworks but is often plagued by poor selectivity. Recent literature paints a promising picture--a more general metal-catalyzed [2+2+2] cycloaddition can be accomplished intermolecularly using three separate alkynes to furnish highly substituted arenas (see scheme).

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