Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds

[Image: see text] The Pd(0)-catalyzed intermolecular C–H amination of unactivated C(sp(3))–H bonds using aryl amines as the nitrogen source is disclosed. Either the C–N cross-coupling product or the C–H amination product could be accessed selectively by adjusting the steric environment of the substrate.