Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework

利用稳健的金属有机框架中可逆的主客体位点交换实现氨储存

阅读:2

Abstract

MFM-300(Al) shows reversible uptake of NH(3) (15.7 mmol g(-1) at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm(-3) at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro-spectroscopy on ND(3) @MFM-300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。