An anion-modulated three-way supramolecular switch that selectively binds dihydrogen phosphate, H2PO4-

一种阴离子调控的三向超分子开关,可选择性地结合磷酸二氢根离子(H2PO4-)。

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Abstract

AN ANIONIC THREE-WAY SWITCH: A bipyridyl bisurea-based anion receptor that is highly selective for dihydrogen phosphate demonstrates spectroscopically distinct anion bound conformations toward halides and select oxoanions. (1)H NMR studies show the differing anion induced conformations are reversible allowing this system to function as a three-way molecular switch.

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