Abstract
xLa(2)O(3)-(100 - x)Ga(2)O(3) binary glasses were synthesized by an aerodynamic levitation technique. The glass-forming region was found to be 20 ≤ x ≤ 57. The refractive indices were greater than 1.92 and increased linearly with increasing x. The polarizabilities of oxide ions were estimated to be 2.16-2.41 Å(3), indicating that the glasses were highly ionic. The glasses were transparent over a very wide range from the ultraviolet to the mid-infrared region. The widest transparent window among the oxide glasses was from 270 nm to 10 μm at x = 55. From the Raman scattering spectra, a decrease in bridging oxide ions and an increase in non-bridging oxide ions were confirmed to occur with increasing La(2)O(3) content. The maximum phonon energy was found to be approximately 650 cm(-1), being one of the lowest among oxide glasses. These results show that La(2)O(3)-Ga(2)O(3) binary glasses should be promising host materials for optical applications such as lenses, windows, and filters over a very wide wavelength range.