Kinetic Analysis for High-Temperature Coarsening of γ″ Phase in Ni-Based Superalloy GH4169

镍基高温合金GH4169中γ″相高温粗化的动力学分析

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Abstract

The growth of precipitates in Ni-based superalloy GH4169 is critical as it controls the mechanical properties and long-term stability of the alloy. In this paper, the coarsening behavior of the main strengthening phase γ″ in the temperature range from 800 °C to 900 °C is investigated. Two heat treatment steps, i.e., pre-precipitation of γ″ phase and coarsening of precipitates at high temperatures, were performed on the GH4169 alloy. It was found that there were three morphological forms of γ″ phase in chronological order: lip-shape, disc-shape, and irregular rectangle-shape with larger size. The coarsening kinetics of γ″ phase followed the Lifshitz-Slyozov-Wagner (LSW) time-law for diffusion-controlled growth, and the activation energies of γ″ phase before and after losing the coherent relationship with matrix were 261 kJ mol(-1) and 271 kJ mol(-1), respectively.

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