Abstract
A total of 28,095 surface soil samples were collected in areas with high natural background levels; the potential ecological risk is generally low, and the high-risk area is small and mainly affected by lead−zinc mines. The contribution to the potential ecological risk factor (RI) is as follows: Hg > Cd > As > Pb > Cu > Ni > Cr > Zn, with noncarcinogenic chronic risks of Cr > As > Cd > Pb > Ni > Cu > Hg > Zn; furthermore, dermal contact is the main pathway of exposure causing health risks. The total carcinogenic risks caused by heavy metals were as follows: Cr > Cd > As > Pb; and the risks posed by Cr, Cd, and As were higher than the threshold value (1.0 × 10−4); people face a higher threat to heavy metals in soils in Zhenxiong, Ludian, Huize, Weixin, and Zhaoyang. The evaluation result of the EPA PMF model shows that the soil heavy metals are mainly composed of five sources, of which basalt, Permian, and Triassic carbonate rock parent material constitute the natural background source, while the mining activities of lead−zinc mines and the emissions of coal burning by residents constitute the anthropogenic source. The contribution was ranked in order of lead−zinc mining (26.7%) > Triassic carbonate (23.7%) > basalt (20.9%) > coal burning and automobile emissions (16.1%) > Permian carbonate (12.6%).