Abstract
Aqueous zinc-ion batteries (ZIBs) have gained significant recognition as highly promising rechargeable batteries for the future due to their exceptional safety, low operating costs, and environmental advantages. Nevertheless, the widespread utilization of ZIBs for energy storage has been hindered by inherent challenges associated with aqueous electrolytes, including water decomposition reactions, evaporation, and liquid leakage. Fortunately, recent advances in solid-state electrolyte research have demonstrated great potential in resolving these challenges. Moreover, the flexibility and new chemistry of solid-state electrolytes offer further opportunities for their applications in wearable electronic devices and multifunctional settings. Nonetheless, despite the growing popularity of solid-state electrolyte-based-ZIBs in recent years, the development of solid-state electrolytes is still in its early stages. Bridging the substantial gap that exists is crucial before solid-state ZIBs become a practical reality. This review presents the advancements in various types of solid-state electrolytes for ZIBs, including film separators, inorganic additives, and organic polymers. Furthermore, it discusses the performance and impact of solid-state electrolytes. Finally, it outlines future directions for the development of solid-state ZIBs.