Electrochemical Investigation of PANI:PPy/AC and PANI:PEDOT/AC Composites as Electrode Materials in Supercapacitors

PANI:PPy/AC 和 PANI:PEDOT/AC 复合材料作为超级电容器电极材料的电化学研究

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作者:Shahbaz Khan, Mohammad Alkhedher, Rizwan Raza, Muhammad Ashfaq Ahmad, Abdul Majid, ElSayed M Tag El Din

Abstract

The electrochemical deposition of the composites polyaniline (PANI):polypyrrole (PPy)/activated carbon (AC) and polyaniline (PANI): 3, 4-polyethylenedioxythiophene (PEDOT)/AC films is carried out in this work. The electrochemical character of the fabricated samples is investigated via cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) using a three-electrode setup. The values of the specific capacitance of the composites PANI:PPy/AC and PANI:PEDOT/AC at a current density of 1 Ag-1 are evaluated as 586 Fg-1 and 611 Fg-1, respectively. The values of energy density are 40 Whkg-1 and 2094 Wkg-1, whereas power density is recorded as 44 Whkg-1 and 2160 Wkg-1 for respective composites PANI:PPy/AC and PANI:PEDOT/AC. Moreover, the respective composites appeared to retain cyclic stabilities of 92% and 90%. This study points to the potential of the prepared composites for application as electrodes in supercapacitors.

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