Fe(3)O(4)@iron-based metal-organic framework nanocomposite [Fe(3)O(4)@MOF (Fe) NC] as a recyclable magnetic nano-organocatalyst for the environment-friendly synthesis of pyrano[2,3-d]pyrimidine derivatives

Fe(3)O(4)@铁基金属有机框架纳米复合材料[Fe(3)O(4)@MOF (Fe) NC]作为可回收的磁性纳米有机催化剂用于吡喃并[2,3-d]嘧啶衍生物的环境友好合成

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Abstract

Various pyrano[2,3-d]pyrimidines were synthesized by the multicomponent reaction of aldehydes, malononitrile, and acidic C-H compounds such as barbituric acid through the tandem Knoevenagel-Michael cyclocondensation pathway in an environmentally friendly reactive medium in the presence of a recoverable nanocomposite. This nanocomposite includes Fe(3)O(4) nanoparticles placed on an organometallic framework. The synthesized Fe(3)O(4)@iron-based metal-organic framework nanocomposite was characterized using scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, a vibrating sample magnetometer, and thermogravimetric analysis.

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