Nano-Silver-Loaded Activated Carbon Material Derived from Waste Rice Noodles: Adsorption and Antibacterial Performance

废弃米粉制备纳米银负载活性炭材料的吸附与抗菌性能

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Abstract

This study demonstrates, for the first time, the conversion of waste rice noodles (WRN) into a cost-effective, nano-silver-loaded activated carbon (Ag/AC) material capable of efficient adsorption and antibacterial activity. The fabrication process began with the conversion of WRN into hydrothermal carbon (HTC) via a hydrothermal method. Subsequently, the HTC was combined with silver nitrate (AgNO3) and sodium hydroxide (NaOH), followed by activation through high-temperature calcination, during which AgNO3 was reduced to nano-Ag and loaded onto the HTC-derived AC, resulting in a composite material with both excellent adsorption properties and antibacterial activity. The experimental results indicated that the incorporation of nano-Ag significantly enhanced the specific surface area of the Ag/AC composite and altered its pore size distribution characteristics. Under optimized preparation conditions, the obtained Ag/AC material exhibited a specific surface area of 2025.96 m2/g and an average pore size of 2.14 nm, demonstrating effective adsorption capabilities for the heavy metal Cr(VI). Under conditions of pH 2 and room temperature (293 K), the maximum equilibrium adsorption capacity for Cr(VI) reached 97.07 mg/g. The adsorption behavior of the resulting Ag/AC fitted the Freundlich adsorption isotherm and followed a pseudo-second-order kinetic model. Furthermore, the Ag/AC composite exhibited remarkable inhibitory effects against common pathogenic bacteria such as E. coli and S. aureus, achieving antibacterial rates of 100% and 81%, respectively, after a contact time of 4 h. These findings confirm the feasibility of utilizing the HTC method to process WRN and produce novel AC-based functional materials.

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