Abstract
A highly active Co/Beta catalyst was prepared via ion-exchange method, in which sodium cations in the beta zeolite framework were replaced by cobalt ions using an aqueous cobalt nitrate solution. Based on XRD, SEM, TEM, XPS, and nitrogen adsorption-desorption analyses, it was confirmed that cobalt species successfully took the place of sodium ions in beta zeolite, while the cobalt species diffused with a uniform dispersion. Strong electronic coupling between cobalt species and zeolite framework oxygen stabilizes Co(2+) sites in the material. The catalysts perform high efficiency in dye Acid Orange II (AO7) degradation reactions, which gives more than 99.5% removal efficiency at room temperature and initial pH within 10 min under low catalyst dosage. The advantages of the Co/Beta catalyst are reasonably attributed to its maximized metal-zeolite synergistic efficiency.