Abstract
The burgeoning electromagnetic pollution from 5G/6G technologies demands lightweight, broadband, and mechanically robust electromagnetic microwave absorbers (EMWAs). Conventional carbon aerogels suffer from structural fragility and inadequate electromagnetic dissipation. Herein, we propose a defect-engineering strategy through precise optimization of the chitosan (CS)/cellulose nanocrystal (CNC) ratio to fabricate elastic boron nitride nanosheet (BNNS)-embedded carbon aerogels. By fixing BNNS content for optimal impedance matching and modulating the CS/CNC ratio of the aerogel, we achieve synergistic control over hierarchical microstructure, defect topology, and electromagnetic response. The aerogel exhibits a wide effective absorption bandwidth (EAB) of 8.3 GHz at a thickness of 3.6 mm and an excellent reflection loss of -52.79 dB (>99.999% attenuation), surpassing most biomass-derived EMWAs. The performance stems from CNC-derived topological defects enabling novel polarization pathways and BNNS-triggered interfacial polarization, while optimal graphitization (I(D)/I(G) = 1.08) balances conductive loss. Simultaneously, the optimal CS/CNC ratio facilitates the formation of a stable and flexible framework. The long-range ordered micro-arch lamellar structure endows the aerogel with promising elasticity, which retains 82% height after 1000 cyclic compression at 50% strain. This work paves the way for biomass-derived carbon aerogels as next-generation wearable and conformal EMWAs with broadband absorption.