Abstract
The development of highly efficacious materials for the removal of toxic heavy metal-based oxo-anions is of utmost importance. Herein, an ionic porous organic polymer (designated as HB-IPOP) was synthesized through a quaternization reaction between hexa(imidazole-1-yl)benzene and 5,5'-Bis(bromomethyl)-2,2'-bipyridine. HB-IPOP exhibited high saturation uptake capacities, specifically 292 mg·g(-1) for Cr(2)O(7)(2-) and 531 mg·g(-1) for ReO(4)(-), and demonstrated exceptional selectivity for both Cr(2)O(7)(2-) and ReO(4)(-). Additionally, HB-IPOP demonstrates high recyclability, allowing its reuse over at least five cycles. DFT calculations confirmed that the superior interaction sites and binding energies of HB-IPOP with Cr(2)O(7)(2-) and ReO(4)(-) outperform the affinities of other competing anions. This theoretical validation aligns with the experimentally observed high capacity and selectivity of HB-IPOP for these oxo-anions. Hence, HB-IPOP emerges as a promising candidate to replace current adsorbent materials in the effective removal of Cr(2)O(7)(2-) and TcO(4)(-) anions from water.