Recycling of Bovine Hair Waste Through the Design of a Compatibilizing Agent for Sustainable Thermoplastic Starch-Untreated Bovine Hair Composites

通过设计一种相容剂实现牛毛废料的回收利用,以制备可持续的热塑性淀粉-未处理牛毛复合材料

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Abstract

Bovine hair waste was chemically modified to obtain a coupling agent (CA) for the compatibilization of thermoplastic starch (TPS)-unmodified bovine hair waste (UH) composites. The composites processed with CA presented improved tensile strength (3.5 MPa) compared to TPS-UH composites without CA (1.25 MPa). An interaction mechanism to describe the improvement in mechanical properties and thermal stability was postulated based on Fourier-transform infrared spectroscopy (FTIR) and density functional theory (DFT). In addition, optical and electron microscopy showed that CA favored the adhesion of UH to TPS. Global results suggested the formation of a CA-UH network that interacts with the TPS matrix. Obtaining composites from waste from the tanning industry can contribute to the development of a more responsible and sustainable industry and represents an opportunity to reduce the environmental impact of one of the most important industries globally. It is worth mentioning that this research is aligned with the sustainable development goals (SDGs) proposed by the United Nations, which promotes sustainable industrialization and the promotion of innovation.

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