Abstract
The high density of the internal structure of new-generation cementitious composites, such as high-performance and ultra-high-performance concretes, necessitates the use of advanced methods for evaluating their transport properties, particularly those employing a gaseous medium. The developed gas permeability method for cement pastes, based on a modified RILEM-Cembureau approach, has proven to be highly accurate, reliable, and extremely sensitive to changes in the porosity characteristics of such composites. The article contains the results of a study of the mass transport capabilities of blended cement pastes, characterised by variable water-cement ratios. Two types of cements were used in the study: with the addition of fly ash and blast furnace slag. Ordinary Portland cement was used as the reference binder. The tests were conducted after long-term curing under natural conditions, i.e., after 90 days and 2 years. The assessment of open porosity was carried out through three techniques: helium pycnometry, mercury intrusion porosimetry, and water saturation. Permeability, on the other hand, was measured using a customized approach tailored for uniform paste materials. Microstructural changes were also analysed in the context of natural hydration carbonation progress. The results presented allowed a quantitative description of the effects of the w/c ratio, the presence of additives, and the progress of hydration and carbonation on the porosity of pastes and their permeability to gas flow. The two-year curing period of the pastes exposed to natural CO(2) resulted in a reduction of the permeability coefficient k ranging from 11% to 74%, depending on the type of cement and the water-to-cement (w/c) ratio. This decrease was caused by the continued progress of hydration and simultaneous carbonation. The results of the research presented are of interest from both an engineering and scientific point of view in the context of long-term microstructural changes and the mass transport abilities of cement pastes associated with these processes. The extensive range of materials compositions investigated makes it possible to analyse the durability and tightness of many cementitious composites over long periods of service.