Abstract
The present work provides insight into the effect of connectivity within isomeric 3,5-bis-(pyridin-2-yl)-phenyl (N^C^N) platinum and palladium complexes on their electron transmission properties within gold|molecule|gold junctions. The ligands 3,5-bis-(4-(methylthio)-pyridin-2-yl)-phenyl hexanoate (L (m) H) and 3,5-bis-(5-(methylthio)-pyridin-2-yl)-phenyl hexanoate (L (p) H) were synthesized and coordinated with either PtCl or PdCl to form complexes Pt (m) , Pt (p) , Pd (m) and Pd (p) . X-ray photoelectron spectroscopy (XPS) measurements evaluated the contacting modes of the molecules in the junctions. A combination of scanning tunneling microscopy-break junction (STM-BJ) measurements and density functional theory (DFT) calculations demonstrate that for the single-molecule S···S contacted junctions metal coordination enhanced the conductance compared with the free ligands. Notably, the higher degree of orbital mixing between the metal center and the ligand π-orbitals in the metal complexes plays a greater role than quantum interference to the extent that the complexes that incorporate ligands substituted with thiomethyl groups in meta positions relative to the pyridine-benzene linkages have a higher conductance than their para-analogs, e.g., Pt (p) -3.8 log-(G/G (0)) and Pt (m) -3.3 log-(G/G (0)), in contrast to the usual conductance trend (para > meta) for purely organic π-electron systems.