Abstract
Polytetrafluoroethylene (PTFE) is a self-lubricating material but has poor wear resistance. The wear resistance of the composites was enhanced by the incorporation of polyetheretherketone (PEEK), whereas the friction-reducing performance was compromised, thus resulting in an inherent trade-off between wear resistance and lubricity. Graphene nanosheets (GNSs) with high strength and lubricity were introduced as a reinforcement for PEEK/PTFE composites. Composite specimens with varying GNS contents were fabricated and characterized for their mechanical and tribological properties and wear morphologies. Combined with molecular dynamics (MD) simulations, the micro-mechanisms were further elucidated. The optimal GNS content was determined to be 2 wt%, which improved the tensile strength by 10.58% and reduced the wear rate by 17.88% compared to PEEK/PTFE. It achieved the synchronous enhancement of mechanical strength and wear resistance while maintaining desirable friction-reducing performance. MD simulation results demonstrated that the strong interfacial interactions between GNSx and the polymer enabled GNSs to adsorb polymer chains and form a dense rigid network with reduced free volume (FV). The mechanical properties were enhanced by efficient load transfer and the suppression of interfacial delamination enabled by this unique structure; meanwhile, wear resistance was improved due to the mitigation of friction-induced molecular chain scission.