Effect of Pulse Plasma Sintering Temperature on Microstructure and Mechanical Properties of Al(2)O(3)-Cu Composites

脉冲等离子体烧结温度对Al₂O₃-Cu复合材料微观结构和力学性能的影响

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Abstract

Al(2)O(3)-Cu ceramic-metal composites containing 2.5 vol.% of a metallic phase were fabricated using the Pulse Plasma Sintering (PPS) method in order to evaluate the influence of sintering temperature on densification, microstructure, and mechanical performance. Consolidation was carried out at 1200 °C, 1250 °C, 1300 °C, and 1400 °C under uniaxial pressure with a short sintering time of 3 min. Regardless of the processing temperature, all composites exhibited very high relative densities exceeding 99% of the theoretical value, indicating the high efficiency of PPS in densifying Al(2)O(3)-Cu systems while suppressing copper leakage. X-ray diffraction confirmed the presence of only two phases, Al(2)O(3) and Cu, with no secondary reaction products. Microstructural observations revealed irregular copper particles and areas of dispersed metallic phase, whose proportion decreased with increasing sintering temperature due to accelerated matrix densification and copper immobilization. Grain growth in the alumina matrix was strongly temperature-dependent, with the average equivalent grain diameter increasing from 0.49 µm at 1200 °C to 2.35 µm at 1400 °C. Hardness decreased from 19.5 ± 2.8 GPa to 12.2 ± 1.6 GPa with increasing temperature, whereas fracture toughness reached a maximum of 5.42 ± 0.65 MPa·m0.5 at 1400 °C. The highest strength under monotonic compression conditions was obtained for samples sintered at 1300 °C, indicating an optimal balance between densification and microstructural coarsening. These results demonstrate that PPS is an effective method for producing dense Al(2)O(3)-Cu composites with tailored microstructure and mechanical properties.

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