Preparation of a Silicon/MXene Composite Electrode by a High-Pressure Forming Method and Its Application in Li(+)-Ion Storage

采用高压成型法制备硅/MXene复合电极及其在锂离子存储中的应用

阅读:1

Abstract

The main component of high-capacity silicon-based electrodes is silicon powder, which necessitates intricate processing to minimize volume growth and powder separation while guaranteeing the ideal Si content. This work uses the an situ high-pressure forming approach to create an MXene/m-Si/MXene composite electrode, where MXene refers to Ti(3)C(2)T(X), and m-Si denotes two-phase mixed nano-Si particles. The sandwich shape promotes silicon's volume growth and stops active particles from spreading. The conductive structure of Ti(3)C(2)T(X) MXene increases the efficiency of charge transfer while reducing internal resistance. After 100 cycles, the composite electrode's original capacity of 1310.9 mAh g(-1) at a current density of 0.5 A g(-1) is maintained at 781.0 mAh g(-1). These findings lay the foundation for further investigations into Si matrix composite electrodes.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。