Development of a CFD simulation for the analysis of CO(2) separation percentage using novel [emim][C(2)N(3)] ionic liquid solution inside the gas-liquid contactor

开发CFD模拟方法,用于分析在气液接触器中使用新型[emim][C₂N₃]离子液体溶液时CO₂的分离率。

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Abstract

Growing emission of environmentally-hazardous greenhouse pollutants (especially CO(2)) has motivated the researchers to apply gas-liquid membrane contactors as an easy-to-operate and cost-effective technique for increasing their separation efficiency from different sources. In the current decades, ionic liquids (ILs) have shown their potential in the gas separation industry owing to their noteworthy advantages such as great capacity, excellent adjustability and suitable thermal/chemical stability compared to commonly-employed amine absorbents. This investigation aims to analytically/numerically determine the separation yield of CO(2) from CO₂/N(2) gaseous flow using novel -Ethyl-3-methylimidazolium dicyanamide ([emim][C(2)N(3)]) IL inside the gas-liquid contactor. To fulfill the ultimate purpose, a CFD simulation has been proposed using COMSOL Multiphysics software to predict the results. Comparison of model outcome with experimental data has shown brilliant concurrence with the average relative deviation of almost 5%. Evaluation of the results has shown the excellent performance of [emim][C(2)N(3)] IL for the removal of CO(2) (Separation efficiency of around 100%). Finally, the effects of some module/membrane parameters on increasing or decreasing the separation efficiency has been studies in detail.

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