Abstract
Choline salts represent sustainable and safe electrolyte systems. In this study, an aqueous 1 M choline nitrate solution was employed to prepare hydrogel polymer electrolytes (HPE) via in situ photopolymerization. To enhance compatibility between the electrolyte and polymer matrix, choline methacrylate was synthesized and used as a functional monomer alongside HEMA and PEGDA. The photocurable formulation contained 70 wt.% electrolyte and 30 wt.% monomer mixture. Subsequent electrolyte uptake increased the electrolyte fraction in the HPE to 87 wt.%. The use of choline methacrylate enabled the formation of transparent HPE with favorable mechanical performance, showing puncture resistance of 0.33 N and 0.28 N at elongations of 7.9 mm and 4.4 mm for samples with 70 and 87 wt.% electrolyte, respectively. High ionic conductivity was achieved, reaching ~18 mS/cm and ~34 mS/cm for HPE with 70 and 87 wt.% electrolyte. Finally, a capacitor assembled with HPE containing 87 wt.% electrolyte demonstrated good operational parameters, confirming the applicability of this system in energy storage devices. This work highlights the potential of choline-based electrolytes and polymerizable choline derivatives as functional components for the design of efficient, safe, and environmentally friendly gel polymer electrolytes.