Abstract
Bio-based ionic conductive hydrogels have attracted significant attention for use in wearable electronic sensors due to their inherent flexibility, ionic conductivity, and biocompatibility. However, achieving a balance between high ionic conductivity and mechanical robustness remains a significant challenge. In this study, we present a simple yet effective strategy for fabricating a polyelectrolyte-chitin double-network hydrogel (CAA) via the copolymerization of acrylamide (AM) and acrylic acid (AA) with chitin in an AlCl(3)-ZnCl(2)-H(2)O ternary molten salt system. The synergistic interactions of dynamic metal ion coordination bonds and hydrogen bonding impart the CAA hydrogel with outstanding mechanical properties, including a fracture strain of 1765.5% and a toughness of 494.4 kJ/m(3), alongside a high ionic conductivity of 1.557 S/m. Moreover, the hydrogel exhibits excellent thermal stability across a wide temperature range (-50 °C to 25 °C). When employed as a wearable sensor, the hydrogel demonstrates a rapid response time (<0.2 s), remarkable durability over 95 cycles with less than 5% resistance drift, and high sensitivity in detecting various human joint motions (e.g., finger, knee, and elbow bending). It presents a scalable strategy for biomass-derived flexible electronics that harmonizes mechanical robustness with electromechanical performance.