Abstract
Rubber tires are fundamental components of modern society and industrial operations, holding an irreplaceable position in the global manufacturing and transportation sectors. The potential for traditional rubber tires to enhance performance is gradually approaching its limits, rendering it challenging to further improve low rolling resistance, high wet-skid resistance, and high wear resistance (called "magic triangle"). Moreover, the reliance on petroleum resources for rubber hinders the sustainable development of rubber tires. In this work, a series of novel polyurethane (PU) elastomers with potential applications in high-performance automotive tires were synthesized by CO(2)-based poly(propylene carbonate) diol and bio-based poly(propylene oxide) glycol (PO3G). The comprehensive influences of PO3G on the thermal, mechanical, rolling resistance, and wear properties of the elastomers were systematically investigated. The results illustrated that increasing the PO3G content significantly enhanced the wear resistance by 98.43% and the wet-skid resistance by 73.21% and reduced the rolling resistance by 15.38% of the elastomers compared to commercial green tires (HT166). The rational design strategy of PU elastomers not only effectively addresses the "magic triangle" challenge in the tire industry but leverages CO(2) to contribute to the sustainable development of the automotive sector.