Synthesis and Characterization of Silica Obtained by Combined Acid-Alkali Treatment of Serpentinite

蛇纹石酸碱联合处理法制备二氧化硅的合成与表征

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Abstract

Serpentinite rocks and their processing waste represent a valuable source of magnesium and silicon; however, their complex composition complicates the efficient recovery of individual components. This study investigates the combined acid-alkali processing of serpentinite waste from the Zhitikara deposit (Kazakhstan). In the acid leaching stage, sulfuric acid enables magnesium extraction, while subsequent treatment with sodium hydroxide (NaOH) facilitates the selective recovery of silica gel formed during acid attack. At the final neutralization step, amorphous silica is precipitated with a yield exceeding 60% of its initial content. The obtained silica was characterized using FTIR spectroscopy, X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), inductively coupled plasma mass spectrometry (ICP-MS, Thermo iCAP-Q), and nitrogen adsorption measurements via the BET method. It was established that the synthesized silica gel, according to the IUPAC classification, belongs to mesoporous materials, possesses a well-developed specific surface area (400 m(2)·g(-1)), and is suitable for adsorption and catalytic applications.

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