1-Ethenyl-2-(methyl-sulfan-yl)-4,4-diphenyl-4,5-di-hydro-1H-imidazol-5-one (Thio-phenytoin analogue): synthesis, structure and Hirshfeld surface analysis

1-乙烯基-2-(甲硫基)-4,4-二苯基-4,5-二氢-1H-咪唑-5-酮(硫代苯妥英类似物):合成、结构和Hirshfeld表面分析

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Abstract

The title mol-ecule, C(18)H(16)N(2)OS, exhibits a slight 'ruffling' of the imidazolone ring, and the lone pair on the tricoordinate nitro-gen atom is involved in N→C π-bonding within the ring. Both the methyl group bonded to sulfur and the vinyl substituent lie very close to the plane of the five-membered ring. In the crystal, C-H⋯O hydrogen bonds form inversion dimers, which are linked into chains extending along the b-axis direction by C-H⋯π(ring) inter-actions. Hirshfeld surface analysis indicates that H⋯H inter-actions account for more than half of the inter-molecular contacts, with C-H⋯π(ring) inter-actions contributing a further quarter of the total.

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