A Dual-Functional Bi(3)TiNbO(9)/Bi(2)MoO(6) Heterojunction for Simultaneous Environmental Remediation and CO(2) Photoreduction

用于同时进行环境修复和CO₂光还原的双功能Bi₃TiNbO₉/Bi₂MoO₆异质结

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Abstract

The development of versatile photocatalysts is crucial for comprehensive solutions to the intertwined challenges of the energy crisis and environmental pollution. This study presents a novel Bi(3)TiNbO(9)/Bi(2)MoO(6) (BTNO/BMO) heterojunction fabricated via a solvothermal method. Advanced characterization techniques verified the successful synthesis of the as-integrated BTNO/BMO heterostructure. The BTNO/BMO composite exhibited superior performance in multiple applications: efficient degradation of tetracycline reaching 90.2%, removal of gaseous nitric oxide (NO), and photocatalytic reduction of carbon dioxide (CO(2)) to carbon monoxide (CO) with a yield of 51.3 μmol·g(-1). The constructed Type-II heterojunction demonstrated a remarkable ability to suppress charge recombination, thereby significantly enhancing the photocatalytic activity. This work highlights the dual-functional capability of the BTNO/BMO heterojunction for simultaneous environmental purification and fuel production, providing a promising material platform and a strategic design concept for sustainable technological development.

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