Structure and Mechanical Properties of Ti-38Zr-(8-10)Nb (at. %) Alloys for Medical Use

用于医疗用途的Ti-38Zr-(8-10)Nb(原子百分比)合金的结构和力学性能

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Abstract

The research described in this article is a continuation of a series of studies on biocompatible materials, focused on finding the optimal alloy composition and heat treatment regimes. The use of materials with a low Young's modulus ensures the long-term safety of the implant by reducing the stress shielding effect, which causes bone resorption. This work investigates the effect of alloying with niobium in the range of (8-10) at. % on the Ti-38Zr alloy, specifically its structure, mechanical properties, Young's modulus, and superelasticity. In this study, plates of the Ti-38Zr-(8-10)Nb (at. %) alloy were investigated after quenching and subsequent annealing. In Ti-38Zr-(8-10)Nb alloys, quenching from 600 °C fixes the β-phase of Ti. In alloys with (8-9)Nb, this is a metastable β-phase, as evidenced by its superelastic behavior under cyclic tension. Annealing at 400 °C leads to a clear decomposition of the quenched high-temperature β-phase in Ti-38Zr-(8-9)Nb alloys into β- and α'-phases. Based on the mechanical test results, it can be inferred that the precipitation of the brittle ω-phase and the α'-phase occur concurrently, since annealing at 400 °C causes a pronounced embrittlement of the Ti-38Zr-(8-9)Nb alloys (with elongation dropping from ~15% to 0.7-2.5%, respectively) alongside a substantial increase in strength (from 500 MPa to 1010 MPa). For the Ti-38Zr-10Nb alloy, the ductility also declines but remains within acceptable limits (from ~14% to ~10%), while the strength rises from 520 MPa to 630 MPa. The Young's modulus of the Ti-38Zr-(8-10)Nb alloy after quenching is ~80 GPa. After annealing, it increases to 95 GPa for alloys with (8-9)Nb, while for 10Nb it remains at approximately 80 GPa.

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