Synthesis and structure of (7aRS)-4-chloro-6-(4-methyl-phen-yl)-6,7,7a,8-tetra-hydro-5H-indeno-[5,6-b]furan-5-one, a fused-ring system arising from a new variant of the IMDAV reaction

(7aRS)-4-氯-6-(4-甲基苯基)-6,7,7a,8-四氢-5H-茚并[5,6-b]呋喃-5-酮的合成与结构,该稠环体系源于IMDAV反应的一种新变体

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Abstract

The asymmetric unit of the title com-pound, C(17)H(14)ClNO(2), contains two mol-ecules, a and b, where the hydro-benzene and pyrrole rings are in screw-boat and half-chair conformations, respectively. In the crystal, C-H⋯O and C-H⋯Cl hy-dro-gen bonds link the mol-ecules into two-dimensional networks, enclosing R (3) (3)(19), R (2) (2)(18) and R (2) (2)(14) ring motifs. Hirshfeld surface analysis revealed that the most important contributions to the crystal packing are from H⋯H (41.4 and 41.5% for mol-ecules a and b, respectively), H⋯C/C⋯H (18.1 and 20.2%), H⋯O/O⋯H (16.0 and 13.4%) and H⋯Cl/Cl⋯H (13.4 and 11.9%) inter-actions.

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