Abstract
During water flooding processes, the high viscosity of heavy oil and significant reservoir heterogeneity often lead to severe water channeling and low sweep efficiency. Addressing the limitations of traditional hydrophobically associating polymer-based profile-control agents-such as significant adsorption loss, mechanical degradation during reservoir migration, resulting in a limited effective radius and short functional duration-this study developed a polymeric graded profile-control agent suitable for highly heterogeneous conditions. The physicochemical properties of the system were comprehensively evaluated through systematic testing of its apparent viscosity, salt tolerance, and anti-aging performance. The microscopic oil displacement mechanisms in porous media were elucidated by combining CT scanning and microfluidic visual displacement experiments. Experimental results indicate that the agent exhibits significant hydrophobic association behavior, with a critical association concentration of 1370 mg·L(-1), and demonstrates a "low viscosity at low temperature, high viscosity at high temperature" rheological characteristic. At a concentration of 3000 mg·L(-1), the apparent viscosity of the solution is 348 mPa·s at 30 °C, rising significantly to 1221 mPa·s at 70 °C. It possesses a salinity tolerance of up to 50,000 mg·L(-1), and a viscosity retention rate of 95.4% after 90 days of high-temperature aging, indicating good injectivity, reservoir compatibility, and thermal stability. Furthermore, within a concentration range of 500-3000 mg·L(-1), the agent can effectively emulsify Gudao heavy oil, forming O/W emulsion droplets with sizes ranging from 40 to 80 μm, enabling effective plugging of pore throats of corresponding sizes. CT scanning and microfluidic displacement experiments further reveal that the agent possesses a graded control function: in the near-wellbore high-concentration zone, it primarily relies on its aqueous phase viscosity-increasing capability to control the mobility ratio; upon entering the deep reservoir low-concentration zone, it utilizes "emulsion plugging" to achieve fluid diversion, thereby expanding the sweep volume and extending the effective treatment period. This research outcome provides a new technical pathway for the efficient development of highly heterogeneous heavy oil reservoirs.