Preparation and Physicochemical Properties of High-Temperature-Resistant Polymer Gel Resin Composite Plugging Material

耐高温聚合物凝胶树脂复合堵塞材料的制备及理化性能

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Abstract

Lost circulation has become one of the important problems restricting the speed and efficiency of oil and gas drilling and production. To address severe drilling fluid losses in high-temperature fractured formations during deep/ultra-deep well drilling, this study developed a high-temperature and high-strength gelled resin gel plugging system through optimized resin matrix selection, latent curing agent, flow regulator, filling material, etc. Comparative analysis of five thermosetting resins revealed urea-formaldehyde resin as the optimal matrix, demonstrating complete curing at 100-140 °C with a compressive strength of 9.3 MPa. An organosilicon crosslsinker-enabled water-soluble urea-formaldehyde resin achieved controlled solubility and flow-cure balance under elevated temperatures. Orthogonal experiments identified that a 10% latent curing agent increased compressive strength to 6.26 MPa while precisely regulating curing time to 2-2.5 h. Incorporating 0.5% rheological modifier imparted shear-thinning and static-thickening behaviors, synergizing pumpability with formation retention. The optimal formula (25% urea-formaldehyde resin, 10% latent curing agent, 10% high-fluid-loss filler, 0.5% rheological modifier) exhibited superior thermal stability (initial decomposition temperature 241 °C) and mechanical integrity (bearing pressure 13.95 MPa in 7 mm wedge-shaped fractures at 140 °C). Microstructural characterization confirmed interlocking crystalline layers through ether-bond crosslinking, providing critical insights for high-temperature wellbore stabilization.

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