Confined microemulsions: pore diameter induced change of the phase behavior

密闭微乳液:孔径引起相行为的改变

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作者:René Haverkamp, Margarethe Dahl, Tim Julian Stank, Jessica Hübner, Peter Strasser, Stefan Wellert, Thomas Hellweg

Abstract

In the present work, the temperature-dependent phase behavior of a C10E4 based microemulsion is studied in different meso-macroporous glasses, as a function of their pore diameter. The phase behavior in these pores is investigated by small-angle X-ray scattering (SAXS). The crucial parameter we discuss based on the SAXS results is the domain size of the bicontinuous phase. Using a simplified model to fit the scattering data, we can observe the microemulsion inside the pores. These experiments reveal a temperature-dependent change in domain sizes of the bicontinuous microemulsion only for large pores.

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